|
ИСТИНА |
Войти в систему Регистрация |
ИСТИНА ПсковГУ |
||
Heterogeneous Reaction of Hydrogen Iodide with a Chlorine Atomстатья
Информация о цитировании статьи получена из
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 15 апреля 2026 г.
- Авторы: Larin I.K., Pronchev G.B., Trofimova E.M., Sevryuk M.B.
- Журнал: Russian Journal of Physical Chemistry B
- Том: 20
- Год издания: 2026
- Издательство: Maik Nauka/Interperiodica Publishing
- Местоположение издательства: Russian Federation
- Первая страница: 26
- Последняя страница: 31
- DOI: 10.1134/S1990793125701398
- Аннотация: Previously, using the method of resonance fluorescence on chlorine atoms to measure the reaction rate constant for hydrogen iodide and chlorine atoms, the authors obtained the following expression for the dependence of k1 on the temperature inside the reactor: k1 = (0.9 ± 0. 2) × 10–11e(2.4 ± 0.5 [kJ/mole])/RT molecule–1 cm3 s–1. It followed from the expression that this reaction rate constant decreases as the temperature in the reactor grows. It was supposed that the reaction under study could proceed on the reactor wall. This hypothesis was confirmed by experiments under conditions when the diffusion time of chlorine atoms toward the reactor wall was significantly longer than the reaction time.
- Добавил в систему: Прончев Геннадий Борисович