Novel β-amino-7-membered carbonates: ring-opening polymerization and copolymers with l-lactide, ε-caprolactone and trimethylene carbonate

Авторы: Serova Valeriia, Mankaev Badma, Agaeva Milana, Chernikova Elena, Berkovich Anna, Alekseyev Roman, Khvostov Aleksei, Timofeev Sergey, Karlov Sergey
Журнал: e-Polymer
Том: 26
Номер: 1
Год издания: 2026
Первая страница: 1
Последняя страница: 11
Номер статьи: 20250078
DOI: 10.1515/epoly-2025-0078
Аннотация: Novel seven-membered cyclic carbonates bearing β-amino-protecting groups (Cbz, Boc) were synthesized from aspartic acid. Their homopolymerization and copolymerization with l-lactide (l-LA), ε-caprolactone (ε-CL), and trimethylene carbonate (TMC) were conducted using stannous octoate catalyst. Both monomers showed high reactivity, reaching complete conversion within 30 min in homopolymerization and producing polymers with controlled molecular weights and narrow dispersity (Đ ≈ 1.4–1.5). Copolymerizations at different ratios yielded copolymers with Mn up to ∼9,100 g/mol. The copolymer microstructure was comonomer-dependent: blocky with ε-CL but statistical with l-LA. All homopolymers and most copolymers were amorphous, with homopolymer glass transition temperatures from 9 °C to 24 °C. These β-amino-substituted seven-membered cyclic carbonates are highly reactive monomers for developing functionalizable, biodegradable polycarbonates with tunable thermal properties for biomedical applications.
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