Improvement of Cyclic Stability of High-Capacity Lithium-Ion Battery Si/C Composite Anode Through Cu Current Collector Perforationстатья
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Дата последнего поиска статьи во внешних источниках: 4 марта 2026 г.
Аннотация:The adoption of silicon-graphite composites as anode materials for the next generation of lithium-ion batteries with enhanced specific capacity requires complex technological efforts in order to mitigate the problem of the quick performance fading of electrodes due to the mechanical degradation of materials. The matter is currently being addressed in terms of electrolyte components, polymer binders, materials structure and morphology itself, as well as current collector design, which differ greatly in cost and scalability. The present work describes the efficacy of Cu foil perforation\u2014a simple, low-cost, and easily scalable approach\u2014as a means of Si/C composite anode performance stabilization during extensive charge-discharge cycling. The NMC||Si/C pouch-type full cells demonstrated over 90% of initial capacity retention after 100 charge-discharge cycles in the case of a 250 \u00b5m perforated Cu foil used as a current collector, compared to only 60% capacity left in the same conditions for plain Cu foil as an anode. The obtained result is related to the prevention of anode material delamination off the foil surface as a result of silicon expansion and contraction, which is achieved through the formation inter-penetrating metal-composite structure and the presence of \u201cstitches\u201d, connecting and holding both sides of the electrode tightly attached to the current collector.