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A Flame-Retardant Cyclophosphazene as an Electrolyte Component for Si-Graphite Anodes for Lithium-Ion Batteriesстатья
Статья опубликована в высокорейтинговом журнале
Статья опубликована в журнале из списка Web of Science и/или Scopus- Авторы: Vlasova Yulia, Potapov Sergei, Kokontsev Mikhail, Isokjanov Shakhboz, Karakulina Olesia, Komayko Alena, Inozemtseva Alina, Savin Viacheslav, Minaeva Lidiya, Ageshina Alexandra, Rzhevskaia Aleksandra, Krivetskiy Valery
- Журнал: International Journal of Molecular Sciences
- Том: 27
- Номер: 1
- Год издания: 2025
- Издательство: MDPI
- Местоположение издательства: Basel, Switzerland
- Первая страница: 28
- Последняя страница: 28
- DOI: 10.3390/ijms27010028
- Аннотация: Silicon-graphite anodes offer a practical route to increase the energy density of lithium-ion batteries (LIBs), but their widespread adoption is hampered by cyclic instability due to huge volume changes of silicon during lithiation/delithiation process. Another fallout of LIBs capacity gain is growing safety concerns due to fire risks, associated with the uncontrolled release of chemical energy. Herein, we test a hexakis(fluoroethoxy)phosphazene (HFEPN) as a multifunctional electrolyte additive designed to mitigate both issues. The flammability of HFEPN-containing electrolytes was evaluated using a self-extinguishing time test, while the electrochemical performance was assessed in Si/C composite||NMC pouch cells under a progressively accelerated cycling protocol. It is shown that the additive fully imparts flame-retardant properties to the electrolyte at a 15 wt% loading. Despite forming a more stable solid–electrolyte interphase (SEI) with enhanced interfacial kinetics the additive did not improve the cycling stability of the Si/C-based cells. The cells with 15 wt% HFEPN retained 43% of capacity after 70 cycles, comparable to 46.5% for the reference electrolyte. The diffusion limitations imposed by the increased electrolyte viscosity are assumed to offset the interfacial benefits of the additive. Thus, alongside the improved synthetic route, this study demonstrates that while HFEPN functions as an effective flame retardant and SEI modifier, its practical benefits for silicon anodes are limited at high concentrations by detrimental effects on electrolyte transport properties and should be improved in future molecular design efforts.
- Добавил в систему: Кривецкий Валерий Владимирович