Аннотация:Gallium oxide is a promising ultra-wide bandgap (UWBG) transparent oxide semiconductor. It is currently being intensively tested for power electronics devices.Epitaxial growth is mainly utilized for their fabrication. The substrate orientation plays a key role in this process, since the monoclinic low symmetrical gallium oxide phase is highly anisotropic in its physical properties.We report homoepitaxial β-Ga2O3 layers, that were grown by HVPE on the native substrates of the (100) and the (¯201) orientations for the first time. The structural properties of thesefilms are compared with the ones grown on conventional (010) oriented substrates. Acquired layers are single-phase and monocrystalline, but they differ significantly in crystal perfection, homogeneity of chemical composition and surface roughness. The highest growth rate has been achieved on the (¯201) plane,whichdemonstratesthe potential of this orientation in device structures.