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Spectroscopic and theoretical studies of potassium sodium l-(+)-tartrate tetrahydrate and l-tartaric acid used as precursors for in situ laser-induced deposition of the catalytically active copper microstructuresстатья
Информация о цитировании статьи получена из
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Дата последнего поиска статьи во внешних источниках: 8 октября 2025 г.
- Авторы: Tumkin Ilya I., Khairullina Evgeniia M., Myund Liubov A., Logunov Lev S., Gordeychuk Dmitrii I., Panov Maxim S., Kochemirovsky Vladimir A.
- Журнал: Optical and Quantum Electronics
- Том: 51
- Номер: 3
- Год издания: 2019
- Издательство: Springer Nature
- Местоположение издательства: Switzerland
- Номер статьи: 89
- DOI: 10.1007/s11082-019-1800-5
- Аннотация: In this work we study the influence of l-(+)-КNaC 4 H 4 O 6 × 4H 2 O (KNaT) and l-H 2 C 4 H 4 O 6 (H 2 T) on the complexation processes occurring during in situ laser-induced catalytic destruction of the organic components of the aqueous solutions with formation of the unsaturated hydrocarbons. For that purpose, ATR-FTIR, Raman, IR, and NIR spectroscopy as well as quantum chemical calculations were implemented. It was observed that hydration of T 2− anion via carboxylate groups is stronger than that via hydroxyl groups. We also established the changes in the spectral characteristics of the absorption bands corresponding to vibrations of T 2− , HT − , and H 2 T, at solid state-liquid and acid-salt transitions, depending on concentration of the solution components and the [OH − ]/[H 2 T] ratio. Finally, it was shown that ethylene is a main product of the catalytic destruction of the copper tartrate complexes.
- Добавил в систему: Кочемировский Владимир Алексеевич