Crystal Structure of a New Modification of Lithium Vanadate Li3(V,P)O4статья
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Дата последнего поиска статьи во внешних источниках: 27 мая 2015 г.
Аннотация:The crystal structure of a new phase of lithium vanadate, phosphate Li3(V,P)O4 obtained by
hydrothermal synthesis in the Li3PO4–Li2CO3–V2O5–H2O system, is studied by Xray diffraction
(R = 0.0298): a = 6.3050(12), b = 10.921(2), and c = 4.9450(10) Å; space group Pbn21, Z = 4, and ρcalc =
2.543 g/cm3. Specific crystal chemical features of the new compound are analyzed in comparison with related
structures having threedimensional tetrahedral frameworks that offer promise as anode materials in lithium
ion batteries.