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Bimetallic neutral and anionic complexes of transition metal (Co, Mn) carbonyls with indium(<scp>iii</scp>) phthalocyanineстатья
Статья опубликована в высокорейтинговом журнале
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Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 20 февраля 2024 г.
- Авторы: Faraonov Maxim A., Yudanova Evgeniya I., Kuzmin Alexey V., Yakushev Ilya A., Khasanov Salavat S., Otsuka Akihiro, Yamochi Hideki, Kitagawa Hiroshi, Konarev Dmitri V.
- Журнал: Dalton Transactions
- Том: 52
- Номер: 34
- Год издания: 2023
- Издательство: Royal Society of Chemistry
- Местоположение издательства: United Kingdom
- Первая страница: 12049
- Последняя страница: 12056
- DOI: 10.1039/d3dt01498c
- Аннотация: Heterobimetallic {[Co(CO)4]−[InIII(Pc2−)]} (1) and (Cp*2Cr+){[Mn(CO)5]−[InIII(Pc•3−)]}·2C6H4Cl2 (2) complexes based on indium(III) phthalocyanine (Pc) were obtained as crystals. The complexes were synthesized by single (1) and double (2) reduction of indium(III) phthalocyanine chloride in the presence of transition metal carbonyls. Complex 1 contains dianionic Pc2− macrocycles. Thus, the coordinated Co(CO)4 carbonyl accepts an electron in the one-electron reduction forming a diamagnetic [Co(CO)4]− anion. Complex 2 contains a heterobimetallic {[Mn(CO)5]−[InIII(Pc•3−)]}− anion and paramagnetic Cp*2Cr+ counter cations. Therefore, in the double reduction, electrons are transferred to Mn(CO)5 forming a diamagnetic [Mn(CO)5]− anion and to the Pc2− macrocycle forming a paramagnetic radical Pc•3− trianion. Such assignments for 1 and 2 are in line with optical spectra, crystal structures and the data of magnetic measurements. The spectrum of 1 in the UV-visible range is similar to that of the starting InIIIClPc. The formation of 2 is accompanied by an essential blue-shift of the Q-band of Pc as well as by the appearance of an intense NIR band at 1005 nm characteristic of Pc•3−. Compound 1 is EPR silent and diamagnetic, whereas the value of the effective magnetic moment of 2 is 4.24μB at 300 K, which corresponds to the contribution of S = 1/2 (Pc•3−) and S = 3/2 (Cp*2Cr+) spins. Both weakly coupled paramagnetic centers (J = −0.41 cm−1) are observed in the EPR spectra.
- Добавил в систему: Юданова Евгения Ивановна