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New Chiral Zwitterionic Phosphorus Heterocycles: Synthesis, Structure, Properties and Application as Chiral Solvating Agentsстатья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 20 февраля 2024 г.
- Авторы: Sheshenev Andrey E., Boltukhina Ekaterina V., Grishina Anastasiya A., Cisařova Ivana, Lyapkalo Ilya M., Hii King Kuok (Mimi)
- Журнал: Chemistry - A European Journal
- Том: 19
- Номер: 25
- Год издания: 2013
- Издательство: John Wiley & Sons Ltd.
- Местоположение издательства: United Kingdom
- Первая страница: 8136
- Последняя страница: 8143
- DOI: 10.1002/chem.201300062
- Аннотация: Abstract A family of new chiral zwitterionic phosphorus-containing heterocycles (zPHC) have been derived from methylene-bridged bis(imidazolines). These structures were unambiguously determined, including single-crystal XRD analysis for two compounds. The stability, acid/base and electronic properties of these dipolar phosphorus heterocycles were subsequently investigated. zPHCs can be successfully employed as a new class of chiral solvating agents for the enantiodifferentiation of chiral carboxylic and sulfonic acids by NMR spectroscopy. The stoichiometry and binding constants for the donor–acceptor complexes formed were established by NMR titration methods.
- Добавил в систему: Boltukhina Ekaterina V.