Prerequisites for Development of Electrochemical Planar Sensor Based on RGO–PPD–SiW Composite for Determining Isoniazid Content in Biological Liquids

Pisarevskaya, E.Y.; Klyuev, A.L.; Efimov, O.N.; Shapagin, A.V.; Andreev, V.N.

Авторы: Pisarevskaya E.Yu, Klyuev A.L., Efimov O.N., Shapagin A.V., Andreev V.N.
Журнал: Russian Journal of Electrochemistry
Том: 59
Номер: 3
Год издания: 2023
Издательство: Maik Nauka/Interperiodica Publishing
Местоположение издательства: Russian Federation
Первая страница: 213
Последняя страница: 221
DOI: 10.1134/S1023193523030102
Аннотация: A new redox-active composite material based on reduced graphene oxide (RGO), poly-o-phenylenediamine (PPD), and silicotungstic acid (SiW) is studied. The SEM data showed an abrupt decrease in the content of oxygen atoms in the composite as compared to pure graphene oxide (GO). This is associated with its reduction to RGO in the course of RGO–PPD–SiW synthesis. A combination of RGO conductivity and redox catalysis due to the electroactive components (PPD and SiW) enables one to develop various sensors by applying RGO–PPD–SiW onto planar electrodes (screen-printed carbon electrodes, SPCE). In this work, the possibility of developing a sensor for the content of antituberculous antibiotic isoniazid (isonicotinicacid hydrazide, INAH) is studied. Using the CVA method, it is shown that the concentrationdependence of isoniazid oxidation current is linear. The electrocatalytic behavior of the composite during the isoniazid oxidation is also supported by the impedance spectroscopy.
Добавил в систему: Писаревская Елена Юрьевна

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Prerequisites for Development of Electrochemical Planar Sensor Based on RGO–PPD–SiW Composite for Determining Isoniazid Content in Biological Liquidsстатья Исследовательская статья

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