Studies on the effect of polyhedral carboranes on the physicochemical properties of polycarboranosiloxanes

Статья опубликована в высокорейтинговом журнале
Статья опубликована в журнале из списка Web of Science и/или Scopus

Авторы: Minyaylo Ekaterina Olegovna, Zubova Valeria, Zaitsev Andrei V., Ol'shevskaya Valentina Antonovna, Nikiforova Galina, Buzin Mikhail I., Anisimov Anton, Muzafarov Aziz
Журнал: Polymer Chemistry
Год издания: 2023
DOI: 10.1039/d2py01539k
Аннотация: In this work, polycarboranosiloxanes (Mn = 25.5 – 31.3 kDa) with well-defined structures and with a various content of carborane moieties (2 – 15 wt. %) were obtained. The TGA and DSC methods were used to study their thermal properties and the rheological behavior of melts s was studied. It was found that as the content of carboranes in the structure of these polymers exceeds 9 wt. %, the crystallization of the siloxane chain is suppressed. Data of rheological studies indicate that phase separation occurs in such hybrid carboranosiloxane systems.
Добавил в систему: Миняйло Екатерина Олеговна

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