The Effect of Solvent Nature on the Adhesive Properties of Binary Styrene-n-Butyl Acrylate Copolymer Films Formed by Casting on Solid Substratesстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 13 мая 2020 г.
Аннотация:Abstract—A methodological approach has been proposed for studying the effect of solvent nature on theadhesive properties of films of binary copolymers with different chain microstructures. The approach is basedon a complex analysis of the thermodynamic work of adhesion in polymer–liquid model systems and theresults of mechanical tests in combination with quantum-chemical calculations. The approach has been usedfor the first time for copolymers of styrene and n-butyl acrylate having gradient and random distributions ofcomonomer units over the chains, with the copolymers being synthesized by radical polymerization withreversible chain transfer. The results obtained have shown that the adhesive properties of the binary copolymerfilms may be regulated by varying the chemical nature of solvents from which they are formed.