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The adsorption of water isotopomers on carbon adsorbentsстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 19 июля 2013 г.
- Авторы: Lanin S.N., Kovaleva N.V., Litvincheva L.A.
- Журнал: Russian Journal of Physical Chemistry A
- Том: 83
- Номер: 2
- Год издания: 2009
- Издательство: Pleiades Publishing, Ltd
- Местоположение издательства: Road Town, United Kingdom
- Первая страница: 281
- Последняя страница: 284
- DOI: 10.1134/S003602440902023X
- Аннотация: Abstract Adsorption isotherms were measured by the gas chromatography method over the temperature range 50–80°C, and isosteric heats of adsorption of water isotopomers were calculated in the region of low coverages on two active carbons (Norit and FAS) with similar volumes of micropores (0.38 and 0.37 cm3/g) but different chemical properties of the surface (the surface of active carbon (AC) Norit is hydrophilic and that of AC FAS, hydrophobic). The isotherms on AC Norit were convex and those on AC FAS concave toward the axis of adsorption. At all equilibrium pressures, the adsorption of H2O and D2O on AC Norit was much higher than on AC FAS. The isotherms of adsorption of H2O and D2O were quite similar on both adsorbents, but the isotherms and heats of adsorption of D2O were slightly higher than those of H2O because of small differences in adsorbate-adsorbent and adsorbate-adsorbate interactions and the structure of adsorbate molecules.
- Добавил в систему: Ланин Сергей Николаевич
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