Selectivity of Catalytically Modified Tin Dioxide to CO and NH3 Gas Mixturesстатья
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Дата последнего поиска статьи во внешних источниках: 22 февраля 2016 г.
Аннотация:This paper is aimed at selectivity investigation of gas sensors, based on chemically
modified nanocrystalline tin dioxide in the detection of CO and ammonia mixtures in air.
Sol-gel prepared tin dioxide was modified by palladium and ruthenium oxides clusters via
an impregnation technique. Sensing behavior to CO, NH3 and their mixtures in air was
studied by in situ resistance measurements. Using the appropriate match of operating
temperatures, it was shown that the reducing gases mixed in a ppm-level with air could be
discriminated by the noble metal oxide-modified SnO2. Introducing palladium oxide
provided high CO-sensitivity at 25–50 °C. Tin dioxide modified by ruthenium oxide
demonstrated increased sensor signals to ammonia at 150–200 °C, and selectivity to NH3 in
presence of higher CO concentrations.