Efficient Nitrogen Doping of Graphene by Plasma Treatmentстатья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 11 января 2016 г.
Аннотация:Doping of pristine materials can change their chemical and electrical properties. Namely
nitrogen doping of graphene results in modulation of electronic properties of graphene. In this work
we present experimental results on nitrogen doped graphene fabricated in two steps. At first, the
graphene samples were synthesized by a chemical vapor deposition method on copper foils. Then
they were treated with ammonia radio frequency discharge plasma. The prepared samples were
investigated by atomic-force microscopy (AFM), scanning electron microscopy (SEM), Raman
spectroscopy, optical absorption spectroscopy including Fourier transform infrared spectroscopy
(FTIR), X-ray and ultraviolet photoelectron spectroscopy. In doped graphene a dependence of Natom
concentration on the treatment parameters has been revealed. A maximum doping level of 3
atomic % has been obtained and the shift of valence band maximum of 0.2 eV was observed at this
concentration of nitrogen.