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The catalytic properties of products of copper acetylenide explosive decomposition (Cu+C) have been investigated in simulated reaction of dehydration-dehydrogenation of propan-2-ol at 60 – 350 grad.C An explosive decomposition of copper acetylenide led to the formation of small amorphous carbon granules and copper particles in it. It was shown, that condition of copper acetylenide explosive decomposition (on air or in vacuum) influenced the selectivity of propan-2-ol decomposition.