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The interface between two immiscible liquids, such as oil and water, is an extremely attractive scaffold to self-assemble nanoparticles (NP) in arranged films. These interfaces are defect-free and pristine by the nature (facilitating reproducibly), they are transparent (advantageous for optical applications), and self-healing (allowing correction of self-assembly errors) as well as mechanically flexible (permitting planar, curved or 3D deformations). Recently, we have proposed a novel tetrathiafulvalene (TTF)-assisted method that leads to self-assembly of gold nanoparticles into cm-scale nanofilms or, so-called, metal liquid-like droplets (MeLLDs). Therefore, this talk will summarize up to date results on MeLLDs investigation and their perspective as well as emerging applications for high sensitive detection with gold porous electrodes, biphasic Raman scattering and colloidosome electrocatalysis
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